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Sputter-deposited cerium vanadium mixed oxide as counter-electrode for electrochromic devices

TitleSputter-deposited cerium vanadium mixed oxide as counter-electrode for electrochromic devices
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication1999
AuthorsMasetti, E., Varsano F., and Decker F.
JournalElectrochimica Acta
Volume44
Pagination3117-3119
ISSN00134686
KeywordsCerium dioxide, Degradation, Electrochemical electrodes, Electrochemistry, Electrochromic device, Electrochromic materials, Electrochromism, Electrooptical devices, Lithium, Mixed oxide, Oxides, Sputter deposition, Thin films, Tungsten compounds, Vanadium oxide
Abstract

Oxide films deposited by reactive radio frequency sputtering of target made of mixed CeO2 and V2O5 (1:1) powders show an anodic electrochromic character upon lithium insertion. As-deposited films look yellowish and become fully transparent for an inserted charge of 30 mC/cm2 of Li ions. A total charge of 60 mC/cm2 has been reversible cycled in the 1 to 5 V versus Li range in an electrochemical cell without any significant degradation. Following these preliminary results, films of Ce-V mixed oxide made by r.f. sputtering are suitable for working in tandem with tungsten oxide in a practical electrochromic device.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0032654625&doi=10.1016%2fS0013-4686%2899%2900028-6&partnerID=40&md5=f620d09ae4887d426acbeabb66c8f2be
DOI10.1016/S0013-4686(99)00028-6
Citation KeyMasetti19993117