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Eumelanin precursor 2-carboxy-5,6-dihydroxyindole (DHICA) as doping factor in ternary (PEDOT:PSS/Eumelanin) thin films for conductivity enhancement

TitoloEumelanin precursor 2-carboxy-5,6-dihydroxyindole (DHICA) as doping factor in ternary (PEDOT:PSS/Eumelanin) thin films for conductivity enhancement
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2020
AutoriMigliaccio, L., Gesuele F., Manini P., Maglione Maria Grazia, Tassini Paolo, and Pezzella A.
RivistaMaterials
Volume13
ISSN19961944
Parole chiave4-ethylenedioxythiophene):poly(styrenesulfonate), Conducting polymers, Conductivity enhancement, Dimethyl sulfoxide, Dimethyl sulfoxide (DMSO), Long-term goals, Melanin, Melanin pigments, Novel strategies, Organic solvents, Oxidative polymerization, Poly(3, Polymer films, Semiconductor doping, Simultaneous integration, Thin films
Abstract

The integration of the pristine not-doped commercial poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) PH1000 with eumelanin, the brown to black kind of melanin pigment, was achieved by dissolving the melanogenic precursors 2-carboxy-5,6-dihydroxyindole (DHICA) in the PH1000 suspension. Solid state oxidative polymerization of the catecholic indole allowed obtaining the ternary blend PEDOT:PSS/eumelanin. The introduction of DHICA into PH1000 produced a noticeable increase in the conductivity of PEDOT thin films akin to that produced by dimethyl sulfoxide (DMSO) treatment, opening up novel strategies for the simultaneous integration of eumelanin polymer and conductivity enhancement of PEDOT containing coatings, as well as the long term goal of replacing PSS by DHICA eumelanin for PEDOT pairing. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85085244352&doi=10.3390%2fma13092108&partnerID=40&md5=04e8af8b9728c559403e495856b6ef40
DOI10.3390/ma13092108
Citation KeyMigliaccio2020