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The carbonatation reaction of layered Na(Mn1/3Fe 2/3)O2: A high temperature study

TitoloThe carbonatation reaction of layered Na(Mn1/3Fe 2/3)O2: A high temperature study
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2011
AutoriVarsano, F., Padella F., La Barbera A., and Alvani C.
RivistaSolid State Ionics
Parole chiaveAbsorption, Carbon dioxide, CO<sub>2</sub> absorption, Comparative analysis, Compounds formation, Controlled conditions, Ferrite, Ferrites, High temperature, High temperature X-ray diffraction, HTXRD, Hydrogen production, In-situ, Manganese, Manganese ferrites, Manganese oxide, Powder composition, Reaction stoichiometry, Sodium, sodium carbonate, Stoichiometry, Termochemical hydrogen production, Thermogravimetric analysis, Transformation kinetics, Weight gain, X ray diffraction, X ray diffraction analysis

The transformation of mixed sodium manganese ferrite into manganese ferrite induced by carbon dioxide was investigated. The reaction was performed in controlled conditions at different temperatures (600 °C and 800 °C). Transformation kinetics were followed in terms of powder composition evolution and weight gain by in-situ high temperature X-ray diffraction and thermogravimetric analysis respectively. Differently than expected by the reaction stoichiometry, the comparative analysis of the obtained experimental results reveals that sodium carbonate and manganese ferrite compounds formation is asynchronous. A mechanism describing mixed sodium manganese oxide transformation into manganese ferrite following sodium extraction by carbon dioxide is proposed and discussed. © 2011 Elsevier B.V. All rights reserved.


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Citation KeyVarsano201119