| Titolo | Hydrated iron phosphates FePO4·nH2O and Fe4(P2O7)3·n H2O as 3 V positive electrodes in rechargeable lithium batteries |
|---|---|
| Tipo di pubblicazione | Articolo su Rivista peer-reviewed |
| Anno di Pubblicazione | 2002 |
| Autori | Masquelier, C., Reale P., Wurm C., Morcrette M., Dupont L., and Larcher D. |
| Rivista | Journal of the Electrochemical Society |
| Volume | 149 |
| Paginazione | A1037-A1044 |
| ISSN | 00134651 |
| Parole chiave | Amorphous materials, Crystalline materials, Cyclic voltammetry, Electric contacts, Electric potential, Electrochemical electrodes, Iron phosphates, Lithium batteries, Lithium insertion, Phosphates, Surface area, Surface properties |
| Abstract | Hydrated Fe111 phosphates were investigated as positive electrode materials in lithium batteries. Reversible lithium insertion into amorphous and crystalline FePO4·nH2O and Fe4(P2O7)3·n H2O compositions was found at potentials between 3.5 and 2.5 V vs. Li+/Li. The roles of (i) specific surface area, (ii) amorphous vs. crystalline state, (iii) H2O content, and (iv) electronic contact between particles in the composite positive electrode, on the electrochemical performances of these materials are discussed. Very stable cycling was obtained for optimized FePO4·1.6H2O and Fe4(P2O7)3·4H2O electrodes at an average voltage of 3.0 and 3.2 V vs. Li+/Li, respectively. |
| Note | cited By 73 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0036689679&doi=10.1149%2f1.1489686&partnerID=40&md5=707cdb5931e51c33418cdde5d11cf743 |
| DOI | 10.1149/1.1489686 |
| Citation Key | Masquelier2002 |
