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Pressureless sintering of ZnO thin film on plastic substrate via vapor annealing process at near-room temperature

TitlePressureless sintering of ZnO thin film on plastic substrate via vapor annealing process at near-room temperature
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2019
AuthorsSico, G., Montanino M., Ventre M., Mollo V., Prontera C.T., Minarini Carla, and Magnani G.
JournalScripta Materialia
Volume164
Pagination48-51
ISSN13596462
KeywordsAnnealing, Costs, Densification evolutions, II-VI semiconductors, Isothermal conditions, Nano particulates, Nanometals, Nanoparticles, Near room temperature, Optical properties, Oxide films, Plastic substrates, Pressure and temperature, Pressure-less sintering, Sintering, Thin films, Vapor annealing, Zinc oxide
Abstract

In this work, Vapor Annealing Sintering (VAS) process was introduced for low-cost pressureless producing dense Zinc Oxide (ZnO) thin films deposited from nanoparticles at near-room temperature (50 °C). Spontaneous densification evolution from nanoparticulate to a dense film via a dissolution-diffusion-reprecipitation mechanism was observed exposing ZnO layers to the vapor of an acetic acid aqueous solution at isothermal condition. The influence of the annealing on the optical properties of the treated films was investigated in order to study the structural changes. The proposed method can allow new opportunities for simple and low-cost ceramics thin film manufacturing also involving pressure and temperature-sensitive materials. © 2019 Elsevier Ltd

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85060523938&doi=10.1016%2fj.scriptamat.2019.01.037&partnerID=40&md5=846443d4e19af66ce6b75d9f75108d68
DOI10.1016/j.scriptamat.2019.01.037
Citation KeySico201948