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Sputter deposition of Pt nanoclusters and thin films on PEM fuel cell electrodes

TitleSputter deposition of Pt nanoclusters and thin films on PEM fuel cell electrodes
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2005
AuthorsAlvisi, Marco, Galtieri G., Giorgi L., Giorgi R., Serra Emanuele, and Signore M.A.
JournalSurface and Coatings Technology
Volume200
Pagination1325-1329
ISSN02578972
KeywordsCatalysts, coating, Cyclic voltammetry, Fuel cells, Gas diffusion electrodes, Morphology, Nanostructured materials, Platinum, Polymer electrolyte fuel cell, Polymer membrane electrodes, Proton-exchange membrane fuel cell (PEMFC) electrodes, Scanning electron microscopy, Sputter deposition, Thin films
Abstract

Sputter deposition was investigated as a tool for manufacturing proton-exchange membrane fuel cell (PEMFC) electrodes with improved performance and better catalyst utilization vs. commercial electrode. Nanosized (diameter 2-5 nm) platinum clusters were deposited on gas diffusion electrodes (carbon paper+PTFE/C diffusive layer). The activity for methanol oxidation was increased about 14 times compared to commercial catalyst, with loading <0.02 mg cm-2. SEM-FEG characterization and cyclic voltammetry were carried out to study the morphology, and the behavior of the Pt clusters as cathodic electrocatalyst of a polymer electrolyte fuel cell. © 2005 Elsevier B.V. All rights reserved.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-28844466455&doi=10.1016%2fj.surfcoat.2005.07.093&partnerID=40&md5=68deb9263878c6237e7764f45a494868
DOI10.1016/j.surfcoat.2005.07.093
Citation KeyAlvisi20051325