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Determination of selected polychlorinated dibenzo-p-dioxins/furans in marine sediments by the application of gas-chromatography-triple quadrupole mass spectrometry

TitleDetermination of selected polychlorinated dibenzo-p-dioxins/furans in marine sediments by the application of gas-chromatography-triple quadrupole mass spectrometry
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2013
AuthorsGuidotti, M., Protano C., Dominici C., Chiavarini Salvatore, Cimino N., and Vitali M.
JournalBulletin of Environmental Contamination and Toxicology
Volume90
Pagination525-530
ISSN00074861
Keywords2, 3, 7, 8 tetrachlorodibenzo para dioxin, article, benzofuran derivative, Benzofurans, Chemical, chemistry, chlorinated dibenzofurans, Dioxins, drug derivative, Environmental monitoring, Environmental sample, Furans, Gas chromatography, Gas Chromatography-Mass Spectrometry, Geologic Sediments, Italy, Marine sediments, mass fragmentography, Mass Spectrometry, methodology, Organic pollutants, Polychlorinated dibenzo p dioxin (PCDDs), Polychlorinated dibenzo-p-dioxins, polychlorodibenzo 4 dioxin, polychlorodibenzo-4-dioxin, Quadrupole mass spectrometry, sediment, Submarine geology, Tetrachlorodibenzodioxin, Triple-quadrupole mass spectrometry, water pollutant, Water Pollutants
Abstract

Selected polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were detected by gas-chromatography coupled to triple quadrupole mass spectrometry (GC-QqQ-MS/MS) in marine sediments collected in central Italy. Total PCDD/Fs concentrations ranged from 11.58 to 193.29 pg/g d.w., with PCDFs as the major contributors in most cases. The congener profiles were characterized by high OCDD (70.7 %-91.4 %). The PCDD/Fs values are within or close to the Environmental Canada sediment reference values (0.85 pg TEQ/g d.w.). GC-QqQ-MS/MS can be a suitable alternative to standard methods for PCDD/Fs determination in environmental samples. The measured PCDD/Fs amounts could be considered as a basis for future monitoring programs. © 2013 Springer Science+Business Media New York.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84876281481&doi=10.1007%2fs00128-012-0956-5&partnerID=40&md5=e1270670c87e520f2748d819c78c916c
DOI10.1007/s00128-012-0956-5
Citation KeyGuidotti2013525