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Nanostructured metal hydride – Polymer composite as fixed bed for sorption technologies. Advantages of an innovative combined approach by high-energy ball milling and extrusion techniques

TitleNanostructured metal hydride – Polymer composite as fixed bed for sorption technologies. Advantages of an innovative combined approach by high-energy ball milling and extrusion techniques
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2017
AuthorsPentimalli, Marzia, Imperi E., Zaccagnini A., and Padella F.
JournalRenewable Energy
Volume110
Pagination69-78
ISSN09601481
Keywordsalloy, Automobile cooling systems, Ball milling, Complexation, composite, Composite materials, cooling, electrochemical method, energy resource, Extrusion, Fuel cells, Heat pump systems, Heat pumps, High thermal conductivity, High-energy ball milling, Hydrides, Hydrogen storage, Low thermal conductivity, Mechanical stability, metal, Metal extrusion, Metal hydrides, Metal recovery, Metals, milling, Milling (machining), nanoparticle, Packed beds, polymer, Polymeric matrices, Polymers, processing, pump, Recovery, renewable resource, Sorption, Thermal conductivity, Thermal conductivity of solids, Thermodynamical properties, thermodynamics, Transportation vehicles, Waste heat, Waste heat utilization
Abstract

Different metal alloys can react highly exothermically and reversibly with hydrogen to form metal hydrides. Based on these reactions several application have been developed, e.g. in fuel cell, in storage for hydrogen gas and in sorption heat pumps. By exploiting the thermodynamical properties of some metal hydriding alloys, cooling energy can be generated by using renewable, sustainable and/or disposable energy sources. However, hydriding alloys show some limitations in their behaviour mainly regarding their intrinsic low thermal conductivity and mechanical stability during the hydriding process. A proper management of these issues is required in practical applications in particular when the metal hydrides have to be stably packed as fixed beds with good mechanical stability, high thermal conductivity, fast kinetics, reproducibility, durability. In this work a composite material containing a high metal fraction is obtained by an innovative bulk and low cost processing approach by combining high-energy ball milling and extrusion techniques. The methodology is presented and the characterization of a representative LaNi5-type based composite is given. The developed composites were used as fixed beds in the implementation of a Metal Hydride Cooling System. Finally, the system was integrated into a refrigerated transportation vehicle, currently under testing. Some results are reported coming from a preliminary test campaign. © 2016 Elsevier Ltd

Notes

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84994099914&doi=10.1016%2fj.renene.2016.07.074&partnerID=40&md5=21e9c71bb8bbfae9713add35b5bcee73
DOI10.1016/j.renene.2016.07.074
Citation KeyPentimalli201769