Influence of Alkyl Chain Length on Microscopic Configurations of the Anion in the Crystalline Phases of PYR1A-TFSI

TitleInfluence of Alkyl Chain Length on Microscopic Configurations of the Anion in the Crystalline Phases of PYR1A-TFSI
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2017
AuthorsPalumbo, O., Trequattrini F., Appetecchi Giovanni Battista, and Paolone A.
JournalJournal of Physical Chemistry C
Volume121
Pagination11129-11135
ISSN19327447
KeywordsAlkyl chain lengths, Bis(trifluoromethane sulfonyl)imide, Crystalline materials, Crystalline phasis, glass, Glass transition, Infrared spectrum, Ionic liquids, Liquids, Microscopic configuration, Mixed systems, Pyrrolidinium-based ionic liquid, Temperature dependence, Temperature distribution
Abstract

The infrared spectra and their temperature dependence are measured for a series of pyrrolidinium based ionic liquids (ILs) sharing the bis(trifluoromethanesulfonyl)imide (TFSI) anion and having alkyl chains of different length. While in the liquid or glassy state, both conformers of TFSI are retained for all compounds, in the solid state a strong predominance of trans-TFSI occurs in ionic liquids with alkyl chains shorter than five C-H groups; on the contrary, for alkyl chain longer than six C-H groups crystalline phases display only cis-TFSI, which is a rare configuration in solids. Moreover, a mixed system composed of a short chain liquid (PYR14-TFSI) with one having a longer chain (PYR18-TFSI) in a mass ratio of 1:1 is studied. The competition between the two conformers of TFSI hinders the crystallization and gives rise to a glass transition around 183 K. © 2017 American Chemical Society.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85020663146&doi=10.1021%2facs.jpcc.7b02365&partnerID=40&md5=e8fdd3c1a8bc61c37d301e7dbf1b7330
DOI10.1021/acs.jpcc.7b02365