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A field screening test for the assessment of concentrations and mobility of potentially toxic elements in soils: a case study on urban soils from Rome and Novi Sad

TitleA field screening test for the assessment of concentrations and mobility of potentially toxic elements in soils: a case study on urban soils from Rome and Novi Sad
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2017
AuthorsMontereali, Maria Rita, Pinto V., Schiavella F., Armiento Giovanna, Angelone Massimo, Crovato Cinzia, Manojlovic M., Cabilovski R., and Cremisini C.
JournalEnvironmental Monitoring and Assessment
Volume189
Pagination1–15
ISSN01676369
Keywordsanalysis, Bioavailability, biochemistry, Biological Availability, Cadmium, Carrier mobility, chemistry, Copper, Dithizone, Environmental monitoring, Extraction, Extraction procedure, Heavy, heavy metal, Heavy metals, In-field screenings, Italy, Lead, Metal content, Metals, mining, Pollution control, procedures, Rome, screening, Serbia, Soil, soil pollutant, Soil Pollutants, Soil pollution, Soil surveys, Soils, urban soils
Abstract

The increasing demand for environmental pollution control results in the development and use of new procedures for the determination of dangerous chemicals. Simple screening methods, which can be used directly in the field for a preliminary assessment of soil contamination, seem to be extremely advantageous. In our laboratory, we developed and optimized a rapid test for a preliminary evaluation of both the concentration and the mobility of some potentially toxic metals in soils. This screening test consists of a single extraction of the soil sample with a buffer solution, followed by the titration of the extracted solution with dithizone to determine the contents of bi-valent heavy metals (such as Pb, Cu, Zn, and Cd). This screening method was then directly applied in the field during the sampling campaign in the framework of an Italian–Serbian collaborative project, finalized in the study of metal availability in soils. The results obtained in the field with the rapid test were compared with those obtained in the laboratory following the conventional procedure commonly used to evaluate metal bioavailability (diethylenetriaminepentaacetic extraction). Moreover, selected samples were analyzed sequentially in the laboratory using the standardized BCR three-step sequential extraction procedure. The screening test gave results conceptually in good agreement with those obtained via the BCR procedure. These preliminary data show that the proposed screening test is a reliable method for the preliminary rapid evaluation of metal total concentrations and of potential metal mobility in soils, supporting sampling activities directly in the field. © 2017, Springer International Publishing AG.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85028081495&doi=10.1007%2fs10661-017-6164-3&partnerID=40&md5=af7d1f3bb44f3cea0f5be3f31a09a325
DOI10.1007/s10661-017-6164-3
Citation KeyMontereali2017