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Binary homogeneous nucleation in water-succinic acid and water-glutaric acid systems

TitleBinary homogeneous nucleation in water-succinic acid and water-glutaric acid systems
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2004
AuthorsGaman, A.I., Kulmala M., Vehkamäki H., Napari I., Mircea Mihaela, Facchini M.C., and Laaksonen A.
JournalJournal of Chemical Physics
Volume120
Pagination282-291
ISSN00219606
KeywordsAerosols, Ammonia, Binary systems, Carboxylic acids, Computer simulation, Crystal lattices, Lattice energies, Nucleation, Reaction kinetics, Solubility, Solutions, surface tension, thermodynamics, Vapor pressure
Abstract

The binary homogeneous nucleation of water-succinic acid and water-glutaric acid systems was investigated for the formation of new particles. Both acids behaved in environment according to their liquid state properties because of the absence of crystalline lattice energies. It was shown that the lack of consistent thermodynamic data for pure organic components and their aqueous solutions represent a high source of uncertainty. The simulations indicate that these binary systems will not form new particles in atmospheric conditions.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0942299411&doi=10.1063%2f1.1630564&partnerID=40&md5=b8880ec4f710d3f47fc59e00e1862955
DOI10.1063/1.1630564
Citation KeyGaman2004282