Layered silver nanoparticles embedded in a BaF<inf>2</inf> matrix: Optical characterization

TitleLayered silver nanoparticles embedded in a BaF2 matrix: Optical characterization
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2009
AuthorsProtopapa, Maria Lucia, Rizzo A., Re Marilena, and Pilloni L.
JournalApplied Optics
KeywordsAbsorption, Ag clusters, Alternate layers, Antireflection coatings, article, Barium compounds, barium derivative, barium fluoride, chemistry, Coatings, Dielectric matrixes, Effective medium theories, Equipment Design, fluoride, Fluorides, instrumentation, Insulator matrix, Layer thickness, Light absorption, matrix, Maxwell-Garnett, metal nanoparticle, Metal nanoparticles, Metallic nanoparticles, Models, Multi-layer devices, Multilayer stacks, Multilayers, Nano-structured, Nanoparticles, Numerical code, Optical absorption spectrum, Optical characterization, Optical materials, Optical Society of America, Optics, Optics and Photonics, Particle shape, Silica, Silica substrate, silver, Silver nanoparticles, Spatial arrangements, surface plasmon resonance, Surface plasmons, Theoretical, theoretical model, Theoretical models, Thermal annealing process, Thermal evaporation, Unsolved problems

Multilayer stacks of silver and BaF2 alternate layers have been deposited by thermal evaporation on a silica substrate with the aim to obtain Ag clusters dispersed in a BaF2 insulator matrix. The Ag layer thickness was approximately 1.2 nm; the thickness of the BaF2 layer was approximately 25nm. The samples were thermally treated for a 1 h thermal annealing process at 500 °C. These kinds of multilayer device also have several applications in the field of optics for the realization of antireflection coatings. However, optical characterization of dielectric matrices that contain layered metallic nanoparticles still remains an unsolved problem in the field of nanostructured optical coatings. Therefore, the surface plasmon resonance peak that appears in the optical absorption spectra because of the formation of Ag nanoclusters inside the BaF2 insulator matrix has been monitored and fitted by numerical codes. In particular, a previously published theoretical model, based on the Maxwell - Garnett effective medium theory, modified to take into account the effects that are due to the particle shapes and the spatial arrangement of the clusters, has been employed to fit the optical absorption spectra. copy; 2009 Optical Society of America.


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