| Title | In situ studies of electrodic materials in Li-ion cells upon cycling performed by very-high-energy x-ray diffraction |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 2001 |
| Authors | Albertini, V.R., Perfetti P., Ronci F., Reale P., and Scrosati B. |
| Journal | Applied Physics Letters |
| Volume | 79 |
| Pagination | 27-29 |
| ISSN | 00036951 |
| Abstract | A very high-energy synchrotron radiation source (87 keV) was utilized for in situ sampling of the structural changes occurring in the electrodic materials of a Li-ion cell during charge-discharge cycling. The real-time evolution of their crystal lattice was obtained as a function of the degree of Li intercalation. As a result, new information on two electrodic materials, Li-Ti "zero strain" and Li-Ni-Co oxide, both of extreme interest for generation of rechargeable batteries, was gained. The actual change of the Li-Ti oxide lattice parameter upon cycling was observed in greater detail than before, and provided evidence of unexpected behavior in some intervals of the cycle. In the Li-Ni-Co sample, a new phase formed during the early stages of cycling that remained stable in the subsequent cycles was revealed. © 2001 American Institute of Physics. |
| Notes | cited By 19 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0035796738&doi=10.1063%2f1.1383058&partnerID=40&md5=c20549c1da5bc8746021b9a63f73deb4 |
| DOI | 10.1063/1.1383058 |
| Citation Key | Albertini200127 |
