| Title | Poly(vinylidene fluoride)-based gel electrolyte membrane for lithium batteries |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 1999 |
| Authors | Appetecchi, Giovanni Battista, Croce F., De Paolis A., and Scrosati B. |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 463 |
| Pagination | 248-252 |
| ISSN | 00220728 |
| Keywords | Chlorine containing polymers, Copolymers, Electric conductivity of solids, Electric potential, Electrochemistry, Fluorine containing polymers, Gelification, Gels, Lithium batteries, Polychlorotrifluoroethylene, Polyelectrolytes, Polyethylenes, Polymer membrane electrodes, Polymeric membranes, Polyvinylidene fluoride, Vinyl resins |
| Abstract | Highly conducting, free standing polymer electrolyte membranes were prepared by gelification of an ethylene carbonate-propylene carbonate lithium methide solution in a poly(vinylidene fluoride)-chlorotrifluoroethylene copolymer matrix. The electrochemical characterization showed that these membranes have a room temperature conductivity of the order of 0.5×10-3 S cm-1, an anodic break-down voltage exceeding 4.7 V vs. Li and good compatibility with the lithium metal electrode. These properties make these membranes of interest for the development of lithium metal and lithium ion batteries. |
| Notes | cited By 46 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0344718050&doi=10.1016%2fS0022-0728%2898%2900412-4&partnerID=40&md5=30a0c5647642825af5f86ba20294dff1 |
| DOI | 10.1016/S0022-0728(98)00412-4 |
| Citation Key | Appetecchi1999248 |
