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Nanoscale organization in piperidinium-based room temperature ionic liquids

TitleNanoscale organization in piperidinium-based room temperature ionic liquids
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2009
AuthorsTriolo, A., Russina O., Fazio B., Appetecchi Giovanni Battista, Carewska M., and Passerini S.
JournalJournal of Chemical Physics
Volume130
ISSN00219606
KeywordsAlkyl chains, Alkylation, Bis(trifluoromethane sulfonyl)imide, Complex natures, Ionic liquids, Ionization of liquids, Ions, Molten state, Nano-scale organizations, Phase diagrams, Polar regions, Room-temperature ionic liquids, Structural orders, Wide angle x-ray scatterings
Abstract

Here we report on the complex nature of the phase diagram of N -alkyl- N -methylpiperidinium bis(trifluoromethanesulfonyl)imide ionic liquids using several complementary techniques and on their structural order in the molten state using small-wide angle x-ray scattering. The latter study indicates that the piperidinium aliphatic alkyl chains tend to aggregate, forming alkyl domains embedded into polar regions, similar to what we recently highlighted in the case of other ionic liquids. © 2009 American Institute of Physics.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-65149091818&doi=10.1063%2f1.3119977&partnerID=40&md5=6e463424edafa033212a75a07c170aaf
DOI10.1063/1.3119977
Citation KeyTriolo2009